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Laser-assisted grafting onto polycarbonate: application to metallization by chemical means

Identifieur interne : 000428 ( France/Analysis ); précédent : 000427; suivant : 000429

Laser-assisted grafting onto polycarbonate: application to metallization by chemical means

Auteurs : M. Charbonnier [France] ; M. Alami [Maroc] ; M. Romand [France] ; J. P. Girardeau-Montaut [France] ; M. Afif [France]

Source :

RBID : ISTEX:1D496B656843DCAFEBF13F64E3D30517FEB9273F

Abstract

Nitrogen atoms were grafted on polycarbonate by laser irradiation (λ=213 nm) through an ammonia atmosphere. The optimal experimental conditions namely ammonia pressure and laser fluence were adjusted for grafting as much nitrogen as possible. The efficiency of the different treatments was estimated by XPS analyses and metallization tests. The latter were carried out by chemical means using a simplified process previously developed in the laboratory within the framework of plasma functionalization of polymer surfaces. This method needs nitrogen atom presence on the surface to be metallized, these atoms allowing the chemisorption of palladium, the latter acting as a catalyst of the metallization reaction (electroless process).

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DOI: 10.1016/S0169-4332(96)00661-7


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ISTEX:1D496B656843DCAFEBF13F64E3D30517FEB9273F

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